Bio­Ko­Red: Use of biochar as a CO2-neu­tral redu­cing agent for the pro­duc­tion of agglo­me­ra­tes from iron-con­tai­ning residues

Fede­ral Minis­try for Eco­no­mic Affairs and Cli­ma­te Action (BMWK), 1 April 2024 to 31 March 2026

Project description

The goal of the pro­ject is to uti­li­ze biochar (also known as plant char­co­al or biochar) as a CO2-neu­tral redu­cing agent in stamp-pres­sed agglo­me­ra­tes made from metall­ur­gi­cal resi­dues and bio­ge­nic bin­ders. For the first time, for­mu­la­ti­ons will be deve­lo­ped using inter­nal fine-grai­ned and iron-rich resi­dues along with sui­ta­ble bio­ge­nic bin­ders to pro­du­ce self-redu­cing agglo­me­ra­tes incor­po­ra­ting biochar, which will then be intro­du­ced into the mel­ting pro­cess of an iron foundry using a hot-blast cupo­la furnace.

The­se agglo­me­ra­tes enable the estab­lish­ment of CO2-neu­tral inter­nal iron recy­cling loops for dust and sludge frac­tions gene­ra­ted in the steel and iron indus­try, which curr­ent­ly must still be land­fil­led due to tech­ni­cal and eco­no­mic rest­ric­tions. The­se mate­ri­al streams often con­tain immense amounts of oxi­dized iron that can poten­ti­al­ly be reco­ver­ed, ther­eby redu­cing the use of pri­ma­ry raw mate­ri­als. To achie­ve this, pre­vious­ly unu­sed bio­ge­nic resi­dues will be pyro­ly­zed, and the resul­ting bio­chars will be used as redu­cing agents. In addi­ti­on to the redu­cing pro­per­ties of biochar, the mecha­ni­cal pro­per­ties such as cold and hot com­pres­si­ve strengths of the pro­du­ced agglo­me­ra­tes are also a focus of inves­ti­ga­ti­on sin­ce the­se para­me­ters affect the fur­nace usa­bi­li­ty of the­se agglo­me­ra­tes. The pro­ject aims to adjust the mecha­ni­cal pro­per­ties through the addi­ti­on of bio­ge­nic bin­ders and sui­ta­ble bio­chars so that the agglo­me­ra­tes are sui­ta­ble for use in mel­ting pro­ces­ses at iron found­ries. Based on the results, tar­ge­ted recipes will be crea­ted, and agglo­me­ra­tes will be pro­du­ced to fur­ther demons­tra­te their usa­bi­li­ty in the steel and iron indus­try. The usa­bi­li­ty of the most pro­mi­sing agglo­me­ra­te for­mu­la­ti­ons will be demons­tra­ted within the pro­ject both at labo­ra­to­ry and pilot sca­le as well as in indus­tri­al-sca­le tri­als through their appli­ca­ti­on in the mel­ting ope­ra­ti­on at Issel­guss Iron Foundry. Throug­hout the enti­re pro­ject dura­ti­on, pro­cess and mate­ri­al para­me­ters will con­ti­nuous­ly be coll­ec­ted to allow for detail­ed eco­lo­gi­cal and eco­no­mic assessments.

With the deve­lo­ped method, lar­ge­ly cli­ma­te-neu­tral secon­da­ry raw mate­ri­als can be imple­men­ted for inter­nal recy­cling of iron car­ri­ers. Fur­ther­mo­re, almost exclu­si­ve­ly resi­du­al mate­ri­als are uti­li­zed in this descri­bed pro­cess, most of which are curr­ent­ly lar­ge­ly unu­sed or only ther­mal­ly pro­ces­sed. This leads to signi­fi­cant impro­ve­ments regar­ding cli­ma­te and envi­ron­men­tal aspects while making a sub­stan­ti­al con­tri­bu­ti­on to bio­e­co­no­my and cir­cu­lar eco­no­my through enhan­ced mate­ri­al flow management.

Approach and Workplan

  • Resi­due and reduc­tant cha­rac­te­ri­sa­ti­on: Com­pre­hen­si­ve phy­si­cal and che­mi­cal ana­ly­sis of tar­get resi­dues (par­tic­le-size dis­tri­bu­ti­on, mine­ra­lo­gy, Fe pha­ses, con­ta­mi­nants) and can­di­da­te biomass/biochar (proximate/ultimate ana­ly­sis, poro­si­ty, sur­face area, ash che­mis­try, reactivity).
  • For­mu­la­ti­on and agglo­me­ra­ti­on: Design recipes that com­bi­ne resi­dues, biochar, and optio­nal addi­ti­ves. Compa­re pres­sing, pel­le­tiz­ing, and alter­na­ti­ve agglo­me­ra­ti­on rou­tes to ensu­re green strength, through­put, and scalability.
  • Per­for­mance and reduc­tion test­ing: Quan­ti­fy poro­si­ty, cold/hot com­pres­si­ve strength, abra­si­on resis­tance, and ther­mal-shock tole­rance. Con­duct stan­dar­di­zed reduc­tion tests to deter­mi­ne the degree of metal­liza­ti­on and reduc­tion kine­tics and assess self-reduc­tion beha­viour and high-tem­pe­ra­tu­re sta­bi­li­ty in a labo­ra­to­ry-sca­le fur­nace to con­firm fur­nace readiness.
  • Sca­le-up and demons­tra­ti­on: Down-sel­ect the most pro­mi­sing for­mu­la­ti­ons for pilot runs, then exe­cu­te an indus­tri­al-sca­le tri­al to pro­ve ope­ra­bi­li­ty and pro­cess inte­gra­ti­on under real plant conditions.
  • Data and assess­ment: Con­ti­nuous­ly coll­ect pro­cess and mate­ri­al data to sup­port a tech­no-eco­no­mic eva­lua­ti­on and an ISO-con­for­mant life-cycle assess­ment (LCA) of cli­ma­te and resour­ce impacts, bench­mark­ed against con­ven­tio­nal coke- or coal-bond­ed agglomerates.

Pro­ject keywords

Iron-bea­ring resi­due recy­cling; Cold-bond­ed agglo­me­ra­ti­on; Self-redu­cing agglo­me­ra­tes; Biomass/Biochar reduc­tants; Toward CO2-neu­tral smelting

Project goals

  • Deve­lop opti­mal agglo­me­ra­te recipes that balan­ce green strength, resis­tance to fur­nace loads, poro­si­ty, and self-reduc­tion potential.
  • Sub­sti­tu­te and opti­mi­ze reduc­tants by scree­ning orga­nic bin­ders and biomass/biochar, and tune dosa­ge to the spe­ci­fic resi­due chemistry.
  • Vali­da­te per­for­mance and reduc­tion beha­viour through stan­dar­di­zed tests (cold and hot com­pres­si­ve strength, abra­si­on, ther­mal shock, degree of metal­liza­ti­on) and lab-sca­le fur­nace trials.
  • Sca­le up and demons­tra­te ope­ra­bi­li­ty through down-sel­ec­tion, pilot runs, and an indus­tri­al-sca­le tri­al inte­gra­ted into exis­ting plant conditions.
  • Quan­ti­fy bene­fits and defi­ne spe­ci­fi­ca­ti­ons with tech­no-eco­no­mic ana­ly­sis and an ISO-con­for­mant LCA, bench­mark­ed against coke- or coal-bond­ed agglo­me­ra­tes, to deli­ver a clear pro­cess win­dow and imple­men­ta­ti­on guidelines.

Project participants

Contact

Yongsu Lee, M.Sc.

 

+49 241 80–25969

lee@iob.rwth-aachen.de

Dr. ‑Ing. Thomas Echterhof

 

+49 241 80–25958

echterhof@iob.rwth-aachen.de

Funding

This pro­ject is fun­ded by the Fede­ral Minis­try of Eco­no­mics and Cli­ma­te Action (BMWK) under the fun­ding code KK5652301VB4.